4 users in 1 row? Not possible. Each user is a database table row. If you mean you want a bottom border or something styled after the 4th row instead of each then you'd need to consult with your template developer. The example below would do the trick, but I've no idea if you have other CSS present that'd conflict.
Code:
.cbUserListTable tbody tr:nth-child(4) {
border-bottom: 1px solid black;
}
Please note the above is a CSS3 selector and only works on modern browsers (IE8, IE9, Chrome, FF, etc..).